FACULTAD
DR. JUAN MANUEL MANRIQUEZ MUJICA


CURRICULUM
LÍNEAS DE INVESTIGACIÓN
PUBLICACIONES
RINCÓN PERSONAL
CURRICULUM
contacto:
-TELÉFONOS: 56-2-6864397- 56-2-6864393
-FAX: 56-2-6864744
-E-MAIL: jmanriqm@puc.cl
grados académico:
- Licenciado en Química: Pontificia Universidad Católica de Chile (1971)
- Químico: Pontificia Universidad Católica de Chile (1971)
- Ph.D.en Química Organometálica de Elementos de Transición :
Instituto Tecnológico de California ( 1976)
categoría académica:
PROFESOR TITULAR
estadas post-doctorales:
- Investigador Asociado, Northwestern University ( Tobin Marks),USA, 1977-1979
- Investigador Visitante Asociado en Química, Instituto Tecnológico de California, USA, 1986
- Científico en Visita en Ciencia de los Materiales C.R.& D.E.I.Du Pont de Nemours and Company, USA,1991
- Científico en Visita, Universidad del Estado de Ohio, USA,1991
resposabilidades docentes:
- Pre-grado: Inorgánica II (Químicos), Química General para Ingeniería
- Post-grado: Inorgánica Avanzada, Organometálica
LINEAS DE INVESTIGACION
 
áreas o líneas de investigación:
Investigador responsable: Proyecto Fondecyt 1020314 (2002-2005)

"Estabilización de especies polimetálicas neutras y de valencia mixta, de hierro,cobalto y niquel,derivadas de s-indacenos por substitución de grupos alquilos en el anillo"

Co-investigador Alterno: Proyecto Fondecyt 1020525

"Estudio De Efectos Cooperativos en Compuestos Biheteronucleares de Anillos Fundidos y su implicancia en Catálisis"

Investigador chileno responsable Proyecto Ecos/Conicyt C01E06

Investigador Proyecto Fondef
investigación actual:

proyectos en curso:

PUBLICACIONES
recientes:
· Síntesis y Caracterización de [Cp*Ru(C8H7)], un Intermediario Util para la Contrucción de Oligómeros Homo y Heteropolinuclear de Ru
F.Burgos, v.Arancibia, JM Manríquez, I.Chávez
Boletín de la Sociedad Chilena de Química, 2000,45,4,621

· Synthesis and Characterization of [Cp*Fedicyclopenta(a,f) naphtha -leneFeCp*] and [Cp*Fedicyclopenta(a,f)naphthaleneFeCp*]BF4 G.Alfonso, I.Chavez, V.Arancibia, JM Manríquez , MT Garland, A. Roig, E.Molins,R.Fortunato Baggio Journal of Organometallic.
Chemistry, 2001, 620,1-2,32-38

· Synthesis and Characterization of Novel p-Phenyllene and p-Biphenlydene-Bridged Germanocenes
J.Rouzaud,A. Castel,P.Riviere,H.Gornitzka , J.M.Manríquez
Organometallics , 2000, 19, 4678-4680

· A New Heterobimetallic Ru,Rh Complex with a Dianionic Pentalene as Bridging Ligand. Synthesis , Crystal Structure and catalytic Activity of (Cp*Ru(h-h5,h3C8H6)Rh(h4COD))
F.Burgos, I. Chávez, M. Valderrama, J.M. Manríquez, F. Delpech, P.Riviere, A. Castel, E. Lago, E. Molins.
Organometallics, 2001,20,1287

- A New Heterobimetallic Ru,Rh Complex with a Dianionic Pentalene as Bridging Ligand. Synthesis , Crystal Structure and catalytic Activity of (Cp*Ru(u-h5,h3C8H6)Rh(h4COD))
Burgos*, I. Chávez*, M. Valderrama*, J.M. Manríquez*, F. Delpech¥, P.Riviere¥, A. Castel¥, E. Lago^, E. Molins^
Organometallics, 2001, 20,1287

- Toward new biosilicones: hydrosilylation of fish oil unsaturated fatty acid ester
Fabien Delpech, Saadia Asgatay, Annie Castel, Pierre Rivire, Monique Riviere-Baudet, Amal Amin -Alami, Juan M.Manríquez
Appl.Organometal.Chem. 2001,15,626-634

- An Effective and Selective Route to 1,5-Dihydropolyalkylated s-Indacenes: Characterization of Their Mono- and Dianions by Silylation. Structure of
trans-1,5-Bis(trimethylsilyl)-2,6-diethyl-4,8-dimethyl-s-indacene
Dahrouch, P.Jara, L.Mendez, Y.Portilla ,D.Abril ,G.Alfonso, I.Chavez, J.M.Manriquez, M.Riviere-Baudet, P.Riviere, A.Castel, J.Rouzaud, H.Gornitzka,
Organometallics, 2001,20,5591-5597

- " New linked digermanocenes and di-stannocenes"
J Rouzand, M. Joudat, A. Castel, P. Riviere, H. Gornitzca, J. M. Manriquez and I. Chavez
Journal of Organometallic Chemistry 651 (2002) 44-51

- Effect of Asymmetry on the Electronic Delocalization in Di-Iron and Iron-Cobalt Mixed Valence Metallocenic Compounds.
Y. Portilla, I. Chávez*, V. Arancibia, B. Loeb, J.M. Manríquez*A. Roig, E. Molins
Inorg. Chem. 2002; 41(7); 1831-1836.
anteriores:
- Paul J. Fagan, Juan M. Manriquez, Eric A. Maatta, Afif M. Seyam and Tobin J. Marks
"Bis[ hydrido(m- hydrido)bis(pentamethylcyclopentadienyl)-actinides (IV)]- [(C5Me5)2AnH (m-H)]2 (An = U, Th).
Synthetic methods of organometallic and Inorganic Chemistry,6,187-188,1997
Volumen Editor: F.T.Edelman, Georg Thieme Verlag Stuttgart-New York 1997

- Structural and Physical Properties of Delocalized Mixed-Valent [Cp*M(pentalene)M'Cp*]n+ and [CpM(Indacene)M'Cp* ]n+ ( M,Mí = F ,Co,Ni ; n = 0 , 1 , 2 ) Complexes
J.uan M. Manriquez , Michael D. Ward , William M. Reiff , Joseph C. Calabrese , Nancy L. Jones , Patrick J. Carrol , Emilio E.Bunel, JoelS.Miller.
J.Am.Chem.Soc. 117,6182,1995

- (h5-Pentamethylcyclopentadienyl)(h5-Cyclopentadienyl) Iron.
J. M. Manriquez , E.E. Bunel , B. Oelckers
Inorganic Synthesis, vol. XXXI, 214,1996.

- "Preparation of a Dinitrogen Complex of Bis (pentamethylcyclopentadienyl) Zirconium (II). Isolation and Protonation Leading to Stoichiometric Reduction of Dinitrogen to Hydrazine".
J.M. ManrÌquez, J.E. Bercaw
J. Am. Chem. Soc. 96, 6229, 1974.

-"Reduction of Carbon Monoxide Promoted by Alkyl and Hydrido Derivatives of Permethylzirconocene".
J. M. ManrÌquez, D. R. Mc. Alister, R. D. Sanner, J. E. Bercaw.
J. Am. Chem. Soc., 100, 2716, 1978.

- "Insertion of Carbon Monoxide into Metal-Nitrogen Bonds. Synthesis, Chemistry, Structures and Structural Dynamics of Bis (Pentamethylcyclopentadienyl) Organoactinide Dialkylamides and h2 - Carbamoyls".
Paul J. Fagan, Juan M. ManrÌquez, Sarah H. Vollmer, Cynthia Secaur Day ,
Victor W. Day,Tobin J. Marks
J. Am. Chem. Soc. 103, 2206, 1981.

- " Pentamethylcyclopentadienylacetylacetonate Complexes of Iron (II), Cobalt (II) and Nickel (II). Convenient Synthetic Entries to Mono-h5 - (C5 Me5 ) Derivatives".
Emilio E. Bunel, Luis Valle, Juan M. ManrÌquez.
Organometallics, 4, 1680, 1985.

- "A Room-Temperature Molecular/Organic-Based Magnet".
Juan M. ManrÌquez, Gordon T. Yee, R.Scott McLean, Arthur.J. Epstein, Joel S.
Miller.Science, 252, 1415, 1991

- On the Way to Delocalized Organometallic Polymers: Triple and Quadruple-decker Pentalene Complexes of Iron and Cobalt.
Beatriz Oelckers, Ivonne Chavez ,Juan M. Manriquez, , Enrique Roman.
Organometallics, 12, 3396, 1993.